Organic synthesis using bridgehead carbocations and bridgehead enones | Zendy

George A. Kraus | Zendy; Y.S. HON | Zendy; Philipp Thomas | Zendy; Steve Laramay | Zendy; Spiros Liras | Zendy; Jeff Hanson | Zendy

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Organic synthesis using bridgehead carbocations and bridgehead enones

Author(s) -

George A. Kraus,

Y.S. HON,

Philipp Thomas,

Steve Laramay,

Spiros Liras,

Jeff Hanson

Publication year - 1989

Publication title -

chemical reviews

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 20.528

H-Index - 700

eISSN - 1520-6890

pISSN - 0009-2665

DOI - 10.1021/cr00097a013

Subject(s) - citation , carbocation , computer science , social media , icon , library science , world wide web , chemistry , organic chemistry , programming language

The development of new pathways by which organic molecules can be stereoselectively constructed remains an important direction for organic chemistry. The palladium-mediated cyclizations of Trost,' Stille? Hegedus,3 Larock," Negishi: and Overman6 and the radical cyclization reactions of Keck,' Stork: Hart: Curran,Io Barton," and Beckwith12 represent important new strategies. A comparatively unstudied strategy is the formation of bicyclic or tricyclic systems via reactive bridgehead intermediates. Disciplines Chemistry | Organic Chemistry | Other Chemistry | Polymer Chemistry

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