Synthesis and Dielectric Properties of Polyimide-Chain-End Tethered Polyhedral Oligomeric Silsesquioxane Nanocomposites

Nanoporous polyhedral oligomeric silsesquioxanes (POSS) containing amine groups (NH2−POSS) were reacted with poly(amic acid) having anhydride end groups to form porous POSS/polyimide nanocomposites. The van der Waals interaction between tethered POSS molecules is incompatible with the polar−polar interaction of imide segments, resulting in a self-assembled system of zigzag shaped cylinders or lamellas about 60 nm long and 5 nm wide, as determined by transmission electron microscopy. The incorporation of 2.5 mol % nanoporous POSS results in a reduction of the dielectric constant of the polyimide nanocomposite from 3.40 for the pure polyimide to 3.09 without any degradation in mechanical strength.