English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The silicon-based connector [Si(p-C6H4CO2)4]4− (L) has been employed in the construction of six new metal−organic framework (MOF) materials, all of which have been characterized by single crystal X-ray diffraction techniques. The isostructural frameworks [Cd2(L)(H2O)2]·(DMA) and [Mn2(L)(H2O)2]·(DMA)2.5, IMP-8Cd and IMP-8Mn, respectively, contain extended [M(CO2)2]n chains, often termed rod SBUs (secondary building units), which are cross-linked into a 3D network by tetrahedral L struts to give microporous networks. In contrast, [Cu2(L)(H2O)2]·(DMA)12 (IMP-9) contains dinuclear paddle-wheel Cu2(CO2)4 SBUs connected together with L struts to give an overall PtS type net. [Me2NH2]2[Cd3(L)2(H2O)2]·(DMA)8(H2O)8, [Me2NH2]2[Zn3(L)2]·(DMF)6, and [Me2NH2]2[Zn3(L)2]·(DMF)3 (IMP-10, IMP-11, and IMP-12, respectively) all contain anionic 3D frameworks which are charge balanced by the presence of dimethylammonium cations within their pores. These dimethylammonium cations arise from the hydrolysis of DMA or DMF, or they...

crystal growth and design

Structural Diversity in Metal−Organic Frameworks Built from Rigid Tetrahedral [Si(p-C6H4CO2)4]4− Struts