Macroporous Carbon Supported Zerovalent Iron for Remediation of Trichloroethylene

Groundwater contamination with chlorinated hydrocarbons has become a widespread problem that threatens water quality and human health. Permeable reactive barriers (PRBs), which employ zerovalent iron, are effective for remediation; however, a need exists to reduce the economic and environmental costs associated with constructing PRBs. We present a method to produce zerovalent iron supported on macroporous carbon using only lignin and magnetite. Biochar-ZVI (BC-ZVI) produced by this method exhibits a broad pore size distribution with micrometer sized ZVI phases dispersed throughout a carbon matrix. X-ray diffraction revealed that pyrolysis at 900 °C of a 50/50 lignin–magnetite mixture resulted in almost complete reduction of magnetite to ZVI and that compression molding promotes iron reduction in pyrolysis due to mixing of starting materials. High temperature pyrolysis of lignin yields some graphite in BC-ZVI due to reduction of carbonaceous gases on iron oxides. TCE was removed from water as it passed thr...