Facile Synthesis and Life Cycle Assessment of Highly Active Magnetic Sorbent Composite Derived from Mixed Plastic and Biomass Waste for Water Remediation
Author(s) -
Ahmed I. Osman,
Ahmed M. Elgarahy,
Neha Mehta,
Ala’a H. AlMuhtaseb,
Ahmed S. AlFatesh,
David W. Rooney
Publication year - 2022
Publication title -
acs sustainable chemistry and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.878
H-Index - 109
ISSN - 2168-0485
DOI - 10.1021/acssuschemeng.2c04095
Subject(s) - sorption , sorbent , biomass (ecology) , char , langmuir adsorption model , adsorption , desorption , raw material , materials science , composite number , pulp and paper industry , chemical engineering , waste management , environmental science , chemistry , organic chemistry , composite material , pyrolysis , geology , oceanography , engineering
Plastic and biomass waste pose a serious environmental risk; thus, herein, we mixed biomass waste with plastic bottle waste (PET) to produce char composite materials for producing a magnetic char composite for better separation when used in water treatment applications. This study also calculated the life cycle environmental impacts of the preparation of adsorbent material for 11 different indicator categories. For 1 functional unit (1 kg of pomace leaves as feedstock), abiotic depletion of fossil fuels and global warming potential were quantified as 7.17 MJ and 0.63 kg CO 2 equiv for production of magnetic char composite materials. The magnetic char composite material (MPBC) was then used to remove crystal violet dye from its aqueous solution under various operational parameters. The kinetics and isotherm statistical theories showed that the sorption of CV dye onto MPBC was governed by pseudo-second-order, and Langmuir models, respectively. The quantitative assessment of sorption capacity clarifies that the produced MPBC exhibited an admirable ability of 256.41 mg g -1 . Meanwhile, the recyclability of 92.4% of MPBC was demonstrated after 5 adsorption/desorption cycles. Findings from this study will inspire more sustainable and cost-effective production of magnetic sorbents, including those derived from combined plastic and biomass waste streams.
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