Dyedauxiliary Group Strategy for the α-Functionalization of Ketones and Esters | Zendy

Lorenzo Di Terlizzi | Zendy; Ivana Cola | Zendy; Carlotta Raviola | Zendy; Maurizio Fagi | Zendy; Stefano Protti | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Dyedauxiliary Group Strategy for the α-Functionalization of Ketones and Esters

Author(s) -

Lorenzo Di Terlizzi,

Ivana Cola,

Carlotta Raviola,

Maurizio Fagi,

Stefano Protti

Publication year - 2021

Publication title -

acs organic and inorganic au

Language(s) - English

Resource type - Journals

ISSN - 2694-247X

DOI - 10.1021/acsorginorgau.1c00020

Subject(s) - silylation , ketene , enol , surface modification , chemistry , aqueous medium , functional group , group (periodic table) , photocatalysis , organic chemistry , aqueous solution , catalysis , combinatorial chemistry , polymer

The synthesis of α-arylketones and α-arylazo esters has been achieved in mixed organic-aqueous media under photocatalyst- and metal-free conditions via visible light activation of arylazo sulfones in the presence of enol silyl ethers and ketene silyl acetals, respectively. The process took place efficiently and exhibits an excellent tolerance for a broad variety of functional groups.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research