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The doping of SiO 2 and Fe 2 O 3 into hydrochars that were produced by the hydrothermal carbonization of cellulose was studied with respect to its impact on the resulting surface characteristics and sorption behavior of CO 2 , CH 4 , and O 2 . During pyrolysis, the structural order of the Fe-doped char changed, as the fraction of highly ordered domains increased, which was not observed for the undoped and Si-doped chars. The Si doping had no apparent influence on the oxidation temperature of the hydrochar in contrast to the Fe-doped char where the oxidation temperature was reduced because of the catalytic effect of Fe. Both dopants reduced the micro-, meso- and macroporous surface areas of the chars, although the Fe-doped chars had larger meso- and macroporosity than the Si-doped char. However, the increased degree in the structural order of the carbon matrix of the Fe-doped char reduced its microporosity relative to the Si-doped char. The adsorption of CO 2 and CH 4 on the chars at temperatures between 273.15 and 423.15 K and at pressures up to 115 kPa was slightly inhibited by the Si doping but strongly suppressed by the Fe doping. For O 2 , however, the Si doping promoted the observed adsorption capacity, while Fe doping also showed an inhibiting effect.

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Influence of Mineral Composition of Chars Derived by Hydrothermal Carbonization on Sorption Behavior of CO2, CH4, and O2