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Ordered Mesoporous Carbon Embedded with Cu Nanoparticle Materials for Electrocatalytic Synthesis of Benzyl Methyl Carbonate from Benzyl Alcohol and Carbon Dioxide
Author(s) -
Qiaoli Hu,
Zhixia Zhang,
Jingjie Zhang,
Shiming Li,
Huan Wang,
Jiaxing Lu
Publication year - 2020
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b03651
Subject(s) - benzyl alcohol , mesoporous material , nanoparticle , materials science , carbonate , carbon dioxide , carbon fibers , alcohol , yield (engineering) , catalysis , inorganic chemistry , chemical engineering , organic chemistry , nanotechnology , chemistry , composite material , metallurgy , composite number , engineering
We prepared a series of ordered mesoporous carbons embedded with different contents of Cu nanoparticles (Cu/OMC- X ) and applied them to electrocatalytic synthesis of benzyl methyl carbonate. The materials were characterized by many measurements, which showed that Cu/OMC- X materials maintain highly ordered mesoporous structures with high surface area and highly dispersed Cu nanoparticles. As expected, the materials exhibit good electrocatalytic performance. The optimal yield of benzyl methyl carbonate reaches 69.7% on Cu/OMC-3.

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