Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources | Zendy

Haibo Mei | Zendy; Jiang Liu | Zendy; Yunjie Guo | Zendy; Jianlin Han | Zendy

Open Access

Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources

Author(s) -

Haibo Mei,

Jiang Liu,

Yunjie Guo,

Jianlin Han

Publication year - 2019

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.9b02442

Subject(s) - sulfonyl , chemistry , styrene , electrochemistry , sodium , catalysis , alkoxy group , combinatorial chemistry , organic chemistry , copolymer , polymer , electrode , alkyl

An eco-friendly method for the synthesis of β-alkoxy sulfones via electrochemical alkoxysulfonylation reaction of styrenes with sodium sulfinates as sulfonyl sources has been established. The reaction is conducted in an undivided cell at room temperature and tolerates a wide scope of styrenes, sodium sulfinates, and alcohols. The reaction does not need any chemical oxidants and transition-metal catalysts, which provides a new and green access to β-alkoxy sulfones.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research