Facile Fabrication of C–TiO2 Nanocomposites with Enhanced Photocatalytic Activity for Degradation of Tetracycline
Author(s) -
Shuaishuai Ma,
Jiandong Gu,
Yingxia Han,
Yuan Gao,
Yuqing Zong,
Zhaolian Ye,
Jinjuan Xue
Publication year - 2019
Publication title -
acs omega
Language(s) - English
Resource type - Journals
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b02411
Subject(s) - photocatalysis , materials science , photodegradation , nanocomposite , x ray photoelectron spectroscopy , high resolution transmission electron microscopy , raman spectroscopy , calcination , chemical engineering , visible spectrum , aqueous solution , transmission electron microscopy , diffuse reflectance infrared fourier transform , specific surface area , nanotechnology , catalysis , chemistry , optics , optoelectronics , organic chemistry , physics , engineering
Visible-lightdriven C-TiO 2 nanocomposites were prepared via a simple calcination and acid etching process. The C-TiO 2 nanocomposites were characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, and high-resolution TEM. The results showed that TiO 2 nanoparticles were combined with a porous carbon layer through surface C-O groups, which facilitates the strong interface interaction. The interface combination of nano-TiO 2 and carbon material increases the specific surface area of nano-TiO 2 , widens the range of light response, and improves the efficiency of light-induced electron migration. The visible-light photocatalytic activity of the prepared photocatalyst was evaluated by the decomposition of tetracycline aqueous solution. Compared with that of pure TiO 2 , the photocatalytic activity of C-TiO 2 nanocomposites was significantly improved. Furthermore, a possible photocatalytic mechanism was also tentatively proposed. This work can promote the development of active photocatalysts under solar light for the photodegradation of environmental pollutants.
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