Generation and Reactions of a Benzodehydrotropylium Ion–Co2(CO)6 Complex | Zendy

Mariam A. Mehdi | Zendy; Eric A. C. Bushnell | Zendy; Sahar Nikoo | Zendy; James W. Gauld | Zendy; James R. Green | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Generation and Reactions of a Benzodehydrotropylium Ion–Co₂(CO)₆ Complex

Author(s) -

Mariam A. Mehdi,

Eric A. C. Bushnell,

Sahar Nikoo,

James W. Gauld,

James R. Green

Publication year - 2019

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.9b02390

Subject(s) - nucleophile , chemistry , ion , series (stratigraphy) , medicinal chemistry , computational chemistry , organic chemistry , catalysis , paleontology , biology

A series of 7-methylenedehydrobenzo[7]annulen-5-ol hexacarbonyldicobalt complexes were generated by Hosomi-Sakurai reactions of allylsilanes containing o -alkynylarylaldehyde-Co 2 (CO) 6 complexes. One of the cyclization products was converted into its corresponding dihydrobenzo[7]annulen-7-ol hexacarbonyldicobalt complex, an immediate precursor to a benzodehydrotropylium-Co 2 (CO) 6 . The cation was generated in situ and reacted with four nucleophiles, and its aromatic stabilization was determined by computational methods.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research