Preparation of Syringaldehyde from Lignin by Catalytic Oxidation of Perovskite-Type Oxides
Author(s) -
Yingxia Li,
Jun-peng Zhu,
Zhongjun Zhang,
Yongshui Qu
Publication year - 2020
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b02379
Subject(s) - syringaldehyde , catalysis , yield (engineering) , lignin , perovskite (structure) , oxide , chemistry , materials science , inorganic chemistry , nuclear chemistry , chemical engineering , organic chemistry , metallurgy , engineering
The influence of different reaction conditions on the yield of syringaldehyde was studied by using perovskite oxide as the catalyst. The optimal reaction conditions are as follows: 0.60 g of dealkali lignin, 0.60 g of 5 wt % theta ring-loaded LaFe 0.2 Cu 0.8 O 3 catalyst, 30 mL of 1.0 mol/L NaOH solution, 160 °C reaction temperature, 0.80 MPa O 2 pressure, and 2.5 h reaction time. Under these conditions, the highest syringaldehyde yield was 10.00%. The recycling performance of the catalyst was studied. It was found by XRD analysis that the catalyst maintained high catalytic activity after four times of use.
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