Open AccessPhase Transfer Ceria-Supported Nanocatalyst for Nitrile Hydration Reaction
Author(s) -
Nikitra Nihalchand Gupta,
Amrin S. Punekar,
Karthik Raja E. K. Raj,
Medha M. Ghodekar,
Vipul S. Patil,
Chinnakonda S. Gopinath,
Thirumalaiswamy Raja
Publication year - 2019
Publication title -
acs omega
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b02173
Subject(s) - catalysis , desorption , x ray photoelectron spectroscopy , raman spectroscopy , materials science , fourier transform infrared spectroscopy , nitrile , phase (matter) , transmission electron microscopy , thermal desorption spectroscopy , scanning electron microscope , adsorption , analytical chemistry (journal) , chemical engineering , chemistry , nanotechnology , organic chemistry , optics , physics , engineering , composite material
The present study elaborates the catalytic effect of rare-earth metal oxides (Sm 2 O 3 and La 2 O 3 ) over ceria as a support phase transfer catalyst. The synthesized catalysts have been subjected to different characterization techniques, such as field-emission scanning electron microscopy, high-resolution transmission electron microscopy, powder X-ray diffraction, N 2 adsorption-desorption (BET surface analysis), temperature-programmed desorption study (NH 3 /CO 2 -TPD), Fourier transform infrared, Raman analysis, and X-ray photoelectron spectroscopy to get better insights into the catalytic activity of the catalysts for hydration of nitrile.
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