Semi-Transparent and Stable Solar Cells for Building Integrated Photovoltaics: The Confinement Effects of the Polymer Gel Electrolyte inside Mesoporous Films
Author(s) -
Huawei Zhou,
Jiawen Cui,
Junxue Guo,
Siwen Tao,
Xiaorui Gao,
Meiqian Liu,
Miaomiao Wang,
Ning Yu,
Xiaojun Wang,
Haoyu Gong,
Yanmin Li,
Ziang Wang,
Tian Liu,
Xun Sun,
Yan Chen,
Jie Yin,
Xianxi Zhang,
Chunyang Zhang,
Yantao Shi
Publication year - 2019
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b01956
Subject(s) - materials science , building integrated photovoltaics , mesoporous material , electrolyte , photovoltaic system , photovoltaics , transmittance , solar cell , energy conversion efficiency , dye sensitized solar cell , chemical engineering , optoelectronics , nanotechnology , electrode , chemistry , engineering , catalysis , ecology , biochemistry , biology
The semi-transparent solar cells are promising to be applied in building integrated photovoltaic (BIPV) and tandem solar cells. In this study, we fabricate semi-transparent and stable solar cells for BIPV by utilizing a poly (ethylene oxide) electrolyte and controlling the size of TiO 2 nanoparticles and the thickness of the TiO 2 film. The power conversion efficiency of the semi-transparent (over 50% transmittance at 620-750 nm) and quasi-solid solar cells is 5.78% under standard AM1.5G, 100 mW cm -2 . The higher conductivity and smaller diffusion resistance of the quasi-solid electrolyte inside the mesoporous TiO 2 film indicate the confinement effects of the polymer electrolyte inside a mesoporous TiO 2 film. The unsealed semi-transparent and quasi-solid solar cell retains its initial efficiency during 1000 h irradiation in humid air.
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