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The ideal product of rare-earth-doped phosphors should have uniform particle size distribution and homogeneous doping ions in each particle, and therefore, intensified micromixing at mesoscale is highly required. In this article, inspired by the concept of "mesoscience", we demonstrate the tuning of Eu 3+ doping in GdBO 3 microparticles at mesoscale by a high-gravity-assisted reactive precipitation-coupled calcination process. The high-gravity environment and tiny droplets generated by the high-gravity rotating packed bed (RPB) reactor lead to significant intensification of mass transfer and micromixing, which are beneficial for the homogeneous doping of Eu 3+ in the host material during reactive precipitation in liquid solution. Under excitation at 395 nm, the emission spectra of the Eu 3+ -doped phosphors exhibit a narrow-band red emission centered at 625 nm and the highest intensity was observed at x = 0.2. The RPB products show higher intensity than that of the control group even when the reaction time was shortened to 1/6. After calculation, the quenching in the sample most likely results from dipole-dipole interactions. The chromaticity coordinates for the RPB sample was measured as (0.598, 0.341) with a quantum yield of up to 78.11%, and the phosphors exhibit good thermal stability at 423 K. The phosphors were used as the luminescent materials for light-emitting diodes (LEDs), and the devices showed good performance. Our preliminary study illustrated that high-gravity-assisted approaches are promising for tuning the doping of rare-earth ions in microparticles at mesoscale toward efficient production of phosphors for LEDs.

Tuning the Doping of Europium in Gadolinium Borate Microparticles at Mesoscale Toward Efficient Production of Red Phosphors