Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube | Zendy

Hui Xue | Zendy; Junze Cao | Zendy; Liang Zhao | Zendy; Haigang Hao | Zendy; Maochun Hong | Zendy

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Conformation-Driven Self-Assembly: From a 1D Metal–Organic Polymer to an Infinite Double Nanotube

Author(s) -

Hui Xue,

Junze Cao,

Liang Zhao,

Haigang Hao,

Maochun Hong

Publication year - 2019

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.9b01344

Subject(s) - nanotube , materials science , polymer , metal , nanotechnology , self assembly , polymer science , chemical physics , carbon nanotube , composite material , chemistry , metallurgy

A novel conformation-driven self-assembly system from a one-dimensional polymer to a metal-organic double nanotube has been developed. DFT calculations indicate that the double nanotube with a syn -conformation of ligands is a thermodynamically favored stable product than a one-dimensional polymer. To the best of our knowledge, this is the first example of the infinite metal-organic double nanotube. In addition, a discrete M 6 L 8 -type cage has also been in situ self-assembled from rationally selected building blocks.

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