Reversible Thermochromism of Nickel(II) Complexes and Single-Crystal-to-Single-Crystal Transformation | Zendy

Jayaraman Pitchaimani | Zendy; Subramanian Karthikeyan | Zendy; N. Lakshminarasimhan | Zendy; Savarimuthu Philip Anthony | Zendy; Dohyun Moon | Zendy; Vedichi Madhu | Zendy

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Reversible Thermochromism of Nickel(II) Complexes and Single-Crystal-to-Single-Crystal Transformation

Author(s) -

Jayaraman Pitchaimani,

Subramanian Karthikeyan,

N. Lakshminarasimhan,

Savarimuthu Philip Anthony,

Dohyun Moon,

Vedichi Madhu

Publication year - 2019

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.9b01263

Subject(s) - thermochromism , differential scanning calorimetry , single crystal , crystallography , raman spectroscopy , nickel , materials science , crystal (programming language) , thermogravimetric analysis , ligand (biochemistry) , chemistry , optics , metallurgy , organic chemistry , thermodynamics , receptor , biochemistry , programming language , physics , computer science

A molecular Ni(II)-NNN pincer complex ( 1 ) exhibited unprecedented reversible single-crystal-to-single-crystal transformation and color change upon heating and cooling due to a subtle change in the N-Ni(II) bond length and ligand conformation. UV-vis, thermogravimetric, differential scanning calorimetry, single-crystal structural data, temperature-dependent powder X-ray diffraction, and Raman and computational studies supported the structural change of the Ni(II) complex with temperature.

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