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We describe the structure and properties of [Zn(C 6 H 4 N 5 )N 3 ]  n  , a new nonporous three-dimensional high-energy metal-organic framework (HE-MOF) with enhanced thermal stability. The compound is synthesized by the hydrothermal method with in situ ligand formation under controlled pH and characterized using single-crystal X-ray diffraction, elemental analysis, and Fourier transform infrared. The measured detonation temperature ( T  det = 345 °C) and heat of detonation (Δ H  det = -0.380 kcal/g) compare well with commercial explosives and other nitrogen-rich HE-MOFs. The velocity and pressure of denotation are 5.96 km/s and 9.56 GPa, respectively. Differential scanning calorimetry analysis shows that the denotation of [Zn(C 6 H 4 N 5 )N 3 ]  n  occurs via a complex temperature-dependent mechanism.

Azide-Based High-Energy Metal–Organic Frameworks with Enhanced Thermal Stability