Novel Technology for the Removal of Brilliant Green from Water: Influence of Post-Oxidation, Environmental Conditions, and Capping

Chemical dyes are used in a wide range of anthropogenic activities and are generally not biodegradable. Hence, sustainable recycling processes are needed to avoid their accumulation in the environment. A one-step synthesis of Fe core -maghemite shell (Fe-MM) for facile, instantaneous, cost-effective, sustainable, and efficient removal of brilliant green (BG) dye from water has been reported here. The homogenous and monolayer type of adsorption is, to our knowledge, the most efficient, with a maximum uptake capacity of 1000 mg·g -1 , for BG on Fe-MM. This adsorbent was shown to be efficient in occurring in time-scales of seconds and to be readily recyclable (ca. 91%). As iron/iron oxide possesses magnetic behavior, a strong magnet could be used to separate Fe-MM coated with BG. Thus, the recycling process required a minimum amount of energy. Capping Fe-MM by hydrophilic clay minerals further enhanced the BG uptake capacity, by reducing unwanted aggregation. Interestingly, capping the adsorbent by hydrophobic plastic (low-density polyethylene) had a completely inverse effect on clay minerals. BG removal using this method is found to be quite selective among the five common industrial dyes tested in this study. To shed light on the life cycle analysis of the composite in the environment, the influence of selected physicochemical factors ( T , pH, h ν, O 3 , and NO 2 ) was examined, along with four types of water samples (melted snow, rain, river, and tap water). To evaluate the potential limitations of this technique, because of likely competitive reactions with metal ion contaminants in aquatic systems, additional experiments with 13 metal ions were performed. To decipher the adsorption mechanism, we deployed four reducing agents (NaBH 4 , hydrazine, LiAlH 4 , and polyphenols in green tea) and NaBH 4 , exclusively, favored the generation of an efficient adsorbent via aerial oxidation. The drift of electron density from electron-rich Fe core to maghemite shells was attributed to be responsible for the electrostatic adsorption of N + in BG toward Fe-MM. This technology is deemed to be environmentally sustainable in environmental remediation, namely, in waste management protocol.