Organic Thin Paper of Cellulose Nanofiber/Polyaniline Doped with (±)-10-Camphorsulfonic Acid Nanohybrid and Its Application to Electromagnetic Shielding
Author(s) -
Taku Omura,
Chi Hoong Chan,
Minato Wakisaka,
Haruo Nishida
Publication year - 2019
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b00708
Subject(s) - polyaniline , materials science , electromagnetic shielding , dopant , nanofiber , polyaniline nanofibers , cellulose , polymerization , aniline , doping , conductive polymer , antistatic agent , in situ polymerization , electrical resistivity and conductivity , chemical engineering , conductivity , electrical conductor , polymer chemistry , composite material , organic chemistry , polymer , optoelectronics , chemistry , electrical engineering , layer (electronics) , engineering
A superior electrical conductivity of 38.5 S/cm and an electromagnetic shielding (EMS) effectiveness of -30 dB (-545 dB/mm) across a wide frequency range of 0-15 GHz, including the X-band, were achieved with thin organic paper of (55 μm) cellulose nanofiber (CNF)/polyaniline (PANI) doped with (±)-10-camphorsulfonic acid nanohybrid. Both electrical conductivity and EMS effectiveness of the PANI-coated CNF were strongly affected by the amount and type of dopant, which could be tunable after fabrication process via simple in situ oxidative polymerization of aniline. Flexible and free-standing film was obtained, since CNF provides good mechanical property without diminishing the electrical property of PANI.
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