Open AccessMetal-Free Synthesis of 1,3-Disiloxanediols and Aryl Siloxanols
Author(s) -
Austin T. Kelly,
Annaliese K. Franz
Publication year - 2019
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b00121
Subject(s) - hydrolysis , silane , aryl , metal , chemistry , base (topology) , catalysis , organic chemistry , polymer chemistry , mathematics , mathematical analysis , alkyl
The first example of metal-free oxidative hydrolysis of hydrido-siloxanes is reported. Both base-catalyzed and organocatalytic hydrolysis methods are demonstrated to transform 1,3-dihydrido-disiloxanes into 1,3-disiloxanediols. The first example of a chemoselective silane hydrolysis is demonstrated.
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