Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF | Zendy

Zhengwang Chen | Zendy; Botao Liu | Zendy; Pei Liang | Zendy; Haiqing Luo | Zendy; Jing Zheng | Zendy; Xiaowei Wen | Zendy; Tanggao Liu | Zendy; GuoTian Luo | Zendy; Min Ye | Zendy

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Construction of N–S and C–N Bonds from Reactions of Benzofuroxans with DMSO or THF

Author(s) -

Zhengwang Chen,

Botao Liu,

Pei Liang,

Haiqing Luo,

Jing Zheng,

Xiaowei Wen,

Tanggao Liu,

GuoTian Luo,

Min Ye

Publication year - 2019

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.8b03353

Subject(s) - reagent , ring (chemistry) , solvent , nitro , chemistry , hemiaminal , atom economy , combinatorial chemistry , aryl , medicinal chemistry , organic chemistry , catalysis , alkyl

Novel ring-opening reactions are achieved employing benzofuroxan as a new type of iminating or aminating reagent. These diverse transformations give access to three types of molecular scaffolds, N -aryl dimethylsulfoximines, methanesulfonamides, and hemiaminal ethers, which are important structural motifs in organic and medicinal chemistry. The procedures feature solvent-involved reactions, easily available starting materials, operational simplicity, high atom economy, and the potential further transformation of nitro group.

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