Quantum Dot–Acrylic Acrylate Oligomer Hybrid Films for Stable White Light-Emitting Diodes
Author(s) -
Cheng-Chun Chou,
Tzong-Liu Wang,
Wen-Janq Chen,
ChienHsin Yang
Publication year - 2019
Publication title -
acs omega
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.8b03241
Subject(s) - photopolymer , materials science , acrylate , nanocomposite , light emitting diode , optoelectronics , quantum dot , color temperature , polymerization , polymer , nanotechnology , composite material , copolymer
White light-emitting diodes (LEDs) have been achieved using photopolymerization. Red and green CdSe/ZnS core-shell quantum dots (QDs) are dispersed in photopolymerized aliphatic acrylic acrylate resins, cured by using 36 W UV light for 1.5 min producing QD-acrylate nanocomposites, and then a hybrid LED device is achieved using the QD-acrylate nanocomposite with two emission wavelengths excited by using a blue InGaN LED chip. The cured QD-acrylate nanocomposite films are characterized by using ultraviolet-visible, fluorescence, scanning electron microscopy, atomic force microscopy, and thermogravimetric analysis measurements. Photopolymerization is conveniently employed to adjust several parameters of the CIE-1931 coordinate ( x , y ), color temperature, and color rending index (CRI). Good white balance of the red-green hybrid device achieves a luminance of 7976 lm/m 2 at a 30 mA working current. The light emission efficiency, CRI, and color temperature of 14%, 47, and 11 204 K, respectively, are attained at this working current.
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