Three-Step Telescoped Synthesis of Monosubstituted Vicinal Diamines from Aldehydes | Zendy

Lledó BouIserte | Zendy; Antonio Latorre | Zendy; Santiago Rodrı́guez | Zendy; Florenci V. González | Zendy

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Three-Step Telescoped Synthesis of Monosubstituted Vicinal Diamines from Aldehydes

Author(s) -

Lledó BouIserte,

Antonio Latorre,

Santiago Rodrı́guez,

Florenci V. González

Publication year - 2019

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.8b03030

Subject(s) - diamine , vicinal , chemistry , amine gas treating , organic chemistry , one step , reaction conditions , combinatorial chemistry , oxidative phosphorylation , catalysis , chemical engineering , biochemistry , engineering

Aldehydes are easily transformed into vicinal diamines and piperazines through a one-pot procedure including a Darzens reaction and treatment with an amine or diamine and then with a reducing agent. Additionally, quinoxalines can be accessed by reaction with 1,2-benzenediamine under oxidative conditions. These transformations are simple methods for the preparation of synthetically interesting monosubstituted diamines, piperazines, and quinoxalines.

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