Two Mercury Antimony Chalcogenides Cs2HgSb4S8 and Cs2Hg2Sb2Se6 with Cesium Cations as Counterions | Zendy

Cui-Xia Du | Zendy; Fei-Yan Qi | Zendy; Juan Chen | Zendy; Menghe Baiyin | Zendy

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Two Mercury Antimony Chalcogenides Cs₂HgSb₄S₈ and Cs₂Hg₂Sb₂Se₆ with Cesium Cations as Counterions

Author(s) -

Cui-Xia Du,

Fei-Yan Qi,

Juan Chen,

Menghe Baiyin

Publication year - 2018

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.8b02059

Subject(s) - antimony , crystallography , ribbon , materials science , x ray crystallography , single crystal , diffraction , crystal structure , absorption spectroscopy , inorganic chemistry , chemistry , optics , physics , composite material

Two novel layer structure compounds, Cs 2 HgSb 4 S 8 and Cs 2 Hg 2 Sb 2 Se 6 , were synthesized in organic solvent under solvothermal conditions. The Cs 2 HgSb 4 S 8 is formed of [HgSb 4 S 8 ] 2- ribbons and S atoms by corner sharing. The Cs 2 Hg 2 Sb 2 Se 6 is made up of [SbHg 2 Se 6 ] 5- ribbon and disorder trigonal-pyramidal SbSe 3 by sharing μ 3 -Se. These compounds are characterized by single-crystal X-ray diffraction, powder X-ray diffraction, solid-state optical absorption spectra, and so on.

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