Open AccessMetal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
Author(s) -
Leiling Deng,
Yunyun Liu
Publication year - 2018
Publication title -
acs omega
Language(s) - English
Resource type - Journals
ISSN - 2470-1343
DOI - 10.1021/acsomega.8b01946
Subject(s) - ketene , alkyl , chemistry , metal , polymer chemistry , organic chemistry
The sulfenylation of the vinyl C-H bond in ketene dithioacetals leading to the synthesis of polythiolated alkenes is achieved via the promotion of molecular iodine. In addition, alkyl thiols also exhibit tolerance to the C-H bond elaboration reaction for the synthesis of corresponding alkylthiolated ketene dithioacetals.
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