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Low-cost and ecofriendly porous biocarbons were fabricated from konjaku flour via precarbonization and potassium hydroxide (KOH) activation. The obtained biocarbon AC K -5 derived from a precarbonized carbon/potassium hydroxide (KOH) mass ratio of 1:5 possessed an ultrahigh specific surface area of 1403 m 2 g -1 and hierarchical porous structures with the existence of micro- to macropores. When AC K -5 was employed as a supercapacitor electrode in 6 M KOH, it showed a high specific capacitance of 216 F g -1 and excellent cycling stability with capacitance retention remaining 93.7% after 5000 cycles. Moreover, the AC K -5 sample acquired a supramaximal specific capacitance of 609 F g -1 , and the high energy density of AC K -5//AC K -5 symmetrical cells reached up to 9.2 Wh kg -1 when p -phenylenediamine serving as a redox electrolyte was added into KOH electrolyte. The reported simple fabrication strategy would leverage a green biomass precursor for the preparation of supercapacitors.

Fabrication of Low-Cost and Ecofriendly Porous Biocarbon Using Konjaku Flour as the Raw Material for High-Performance Supercapacitor Application