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Herein, we report the synthesis and characterization of a chemosensor, 5-(diethylamino)-2-(2,3-dihydro-1 H -perimidin-2-yl)phenol (H L ), synthesized from a condensation between 4-(diethylamino)salicylaldehyde and 1,8-diaminonaphthalene. Upon investigation of the sensing properties of H L , it was found that this sensor may be employed for simple yet efficient detection of Cu 2+ in aqueous methanol solutions. The selective and ratiometric response to Cu 2+ yielded an outstandingly low limit of detection of 3.7 nM by spectrophotometry and is also useful as a naked-eye sensor from 2.5 μM. The system was studied by spectrophotometric pH titrations to determine Cu 2+ binding constants and complex speciation. Binding of Cu 2+ to H L occurs in 1:1 stoichiometry, in good agreement with high-resolution electrospray ionization mass spectrometry (ESI-HRMS) results, Cu 2+ titrations, and Job's plot experiments, while the coordination geometry was tentatively assigned as square pyramidal by spectroscopic studies.

Ultrasensitive Colorimetric and Ratiometric Detection of Cu2+: Acid–Base Properties, Complexation, and Binding Studies

Ultrasensitive Colorimetric and Ratiometric Detection of Cu²⁺: Acid–Base Properties, Complexation, and Binding Studies