Incorporation of Carbon Quantum Dots for Improvement of Supercapacitor Performance of Nickel Sulfide
Author(s) -
Srikant Sahoo,
Ashis Kumar Satpati,
Prasanta Kumar Sahoo,
Prakash D. Naik
Publication year - 2018
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.8b01238
Subject(s) - supercapacitor , quantum dot , nickel sulfide , materials science , composite number , tafel equation , capacitance , nickel , carbon fibers , nanotechnology , hydrothermal circulation , nanostructure , sulfide , carbon quantum dots , chemical engineering , electrochemistry , electrode , composite material , metallurgy , chemistry , engineering
A facile hydrothermal method is adopted for the synthesis of hierarchical flowerlike nickel sulfide nanostructure materials and their composite with carbon quantum dot (NiS/C-dot) composite. The composite material exhibited good performance for electrochemical energy-storage devices as supercapacitor with a specific capacity of 880 F g -1 at a current density of 2 A g -1 . The material remained stable up to the tested 2000 charge-discharge cycles. Carbon quantum dots of size 1.3 nm were synthesized from natural sources and the favorable electronic and surface property of C-dots were utilized for improvement of the supercapacitor performance of NiS. The results from Tafel analysis, double-layer capacitance, and the impedance measurement reveal that the incorporation of C-dots inside the NiS matrix has improved the charge-transfer process, which is mainly responsible for the enhancement of the supercapacitive property of the composite materials.
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