Open AccessRu(II)-Catalyzed Oxidative Functionalization of Arylhydrazine-1,2-dicarboxylates with Internal Alkynes for the Synthesis of Enecarbamates
Author(s) -
C. Ravikumar Reddy,
Balasubramanian Sridhar,
Basi V. Subba Reddy
Publication year - 2018
Publication title -
acs omega
Language(s) - English
Resource type - Journals
ISSN - 2470-1343
DOI - 10.1021/acsomega.8b01118
Subject(s) - stereoselectivity , surface modification , catalysis , chemistry , oxidative phosphorylation , medicinal chemistry , combinatorial chemistry , organic chemistry , biochemistry
A novel method has been developed for the synthesis of highly substituted enecarbamates and trisubstituted alkenes from arylhydrazine-1,2-dicarboxylates and 1,2-disubstituted alkynes through a sequential C-C and C-N bond formation. It is entirely a new strategy to produce enecarbamates in a highly regio- and stereoselective manner.
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