Unsubstituted Bambusurils: Post-Macrocyclization Modification of Versatile Intermediates
Author(s) -
Václav Havel,
Tereza Sadilová,
Vladimír Šindelář
Publication year - 2018
Publication title -
acs omega
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.8b00497
Subject(s) - chemistry , derivative (finance) , combinatorial chemistry , copper , surface modification , nitrogen , click chemistry , stereochemistry , medicinal chemistry , polymer chemistry , organic chemistry , financial economics , economics
A new bambusuril derivative, (H)BU[6] , lacking substituents on the ureidic nitrogen atoms, has been isolated and characterized. This macrocycle was prepared by the deprotection of bambusuril (PMB)BU[6] . (H)BU[6] is attractive for use as a starting compound for the preparation of other bambusuril derivatives, which was demonstrated via propargylation and the copper-catalyzed click reaction performed on the macrocycle.
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