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Influence of Molecular Weight on Structure and Catalytic Characteristics of Ordered Mesoporous Carbon Derived from Lignin
Author(s) -
Hengfei Qin,
Ruihong Jian,
Jirong Bai,
Jianghong Tang,
Yue Zhou,
Binglong Zhu,
Dejian Zhao,
Zhijiang Ni,
Liangbiao Wang,
Weiqiao Liu,
Quanfa Zhou,
Xi Li
Publication year - 2018
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.7b01870
Subject(s) - mesoporous material , lignin , carbon fibers , materials science , catalysis , chemical engineering , nanoreactor , mesoporous organosilica , nanotechnology , chemistry , organic chemistry , mesoporous silica , composite material , composite number , engineering
Bio-renewable lignin has been used as a carbon source for the preparation of porous carbon materials. Nevertheless, up to now, there are few studies about the influence of molecular weight of lignin on the structure and morphology of the ordered mesoporous carbon. Here, we synthesized the ordered mesoporous carbon derived from different molecular weights of lignin and Pluronic F127. Fortunately, we found that molecular weight is an important factor for obtaining highly ordered channels, high specific surface area, and ordered mesoporous carbon. More importantly, the narrow well-defined mesoporous channel could exert a spatial restriction effect to some extent, which can serve as nanoreactors for efficient reactions and enhance catalytic performance. The highly ordered mesoporous carbon from lignin is a good candidate for Fischer-Tropsch synthesis catalyst supports.

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