Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide | Zendy

Takeo Sakai | Zendy; Yoshihiro Nagao | Zendy; Yuki Nakamura | Zendy; Yuji Mori | Zendy

Open Access

Methanolysis of the Cyclic Acetal Function of NanoKid Catalyzed by NanoGoblin, the Pyridinium Salt of Tetracyanocyclopentadienide

Author(s) -

Takeo Sakai,

Yoshihiro Nagao,

Yuki Nakamura,

Yuji Mori

Publication year - 2017

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.7b01748

Subject(s) - acetal , pyridinium , moiety , catalysis , salt (chemistry) , methanol , chemistry , organic chemistry , medicinal chemistry

Small, "doll"-shaped tetracyanocyclopentadienide bearing a 1,3-dioxane acetal "head" and cyano "hands" and "feet" was synthesized. Its pyridinium salt, which was named NanoGoblin, exhibited catalytic activity in the methanolysis of acetals, as demonstrated by the reaction with NanoKid in methanol- d 4 , where the acetal head of NanoKid was converted to a deuterated dimethyl acetal moiety.

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