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A chemoselective synthesis of fused novel tricyclic motifs via a facile domino intramolecular cyclization is presented. The strategy enables the formation of dual C-C bond via intramolecular Friedel-Crafts alkylation followed by acylation to accomplish fused tricyclic ketones. Significantly, these fused tricyclic compounds are ubiquitous and constitute major structural cores of natural products.

Brønsted Acid-Mediated Domino One-Pot Dual C–C Bond Formation: Chemoselective Synthesis of Fused Tricyclic Ketones