Amplified Chemiluminescence Signal for Sensing Fluoride Ions | Zendy

Ilke Simsek Turan | Zendy; Özlem Seven | Zendy; Seylan Ayan | Zendy; Engin U. Akkaya | Zendy

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Amplified Chemiluminescence Signal for Sensing Fluoride Ions

Author(s) -

Ilke Simsek Turan,

Özlem Seven,

Seylan Ayan,

Engin U. Akkaya

Publication year - 2017

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.7b00537

Subject(s) - chemiluminescence , fluoride , signal (programming language) , ion , dioxetane , chemistry , photochemistry , analytical chemistry (journal) , optoelectronics , materials science , inorganic chemistry , computer science , chromatography , organic chemistry , programming language

Bringing together the concepts of self-immolative linkers and chemiluminogen dioxetane modules, a chemiluminescence-based sensor for fluoride with signal amplification is presented. Signal amplification is obtained by triggering two chemiluminescence events for each reacting fluoride ion that in turn releases two fluoride ions for each ion. As expected, the chemiluminescence signal starts to rise following an induction period. In addition to the analytical potential, this chemical system is also of interest as a demonstration of positive feedback loop character.

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