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Orientation Control of Two-Dimensional Perovskites by Incorporating Carboxylic Acid Moieties
Author(s) -
Ryosuke Arai,
Masahiro YoshizawaFujita,
Yuko Takeoka,
Masahiro Rikukawa
Publication year - 2017
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.7b00421
Subject(s) - perovskite (structure) , dimer , hydrogen bond , orientation (vector space) , materials science , thermal stability , quantum dot , structural stability , chemical physics , chemical engineering , nanotechnology , chemistry , crystallography , molecule , organic chemistry , geometry , mathematics , structural engineering , engineering
Two-dimensional perovskite compounds, (RNH 3 ) 2 PbX 4 , have attracted much attention as quantum confinement materials. To achieve suitable orientation and exciton properties for optical applications, carboxy groups were introduced into the ammonium cations of two-dimensional perovskite compounds, which formed dimer structures based on the hydrogen bonding by the carboxy moieties. This structural organization allowed control of the layer orientation for favorable solar cells and thermal stability of the perovskites, while maintaining quantum confinement effects.

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