Substrate-Selective C–H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components | Zendy

Konstantin V. Luzyanin | Zendy; Aleksei N. Marianov | Zendy; P. G. Kislitsyn | Zendy; Valentine P. Ananikov | Zendy

Open Access

Substrate-Selective C–H Functionalization for the Preparation of Organosulfur Compounds from Crude Oil-Derived Components

Author(s) -

Konstantin V. Luzyanin,

Aleksei N. Marianov,

P. G. Kislitsyn,

Valentine P. Ananikov

Publication year - 2017

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.7b00137

Subject(s) - organosulfur compounds , substrate (aquarium) , surface modification , selectivity , sulfur , chemistry , raw material , organic chemistry , catalysis , oceanography , geology

The direct utilization of a natural feedstock in organic synthesis is an utmost challenge because the selective production of one product from a mixture of starting materials requires unprecedented substrate selectivity. In the present study, a simple and convenient procedure is evaluated for the substrate-selective alkenylation of a single component in a mixture of organosulfur compounds. Pd-catalyzed alkenylation of two-, three-, four-, and five-component mixtures of crude oil-derived sulfur species led to the exclusive C-H functionalization of only one compound. The observed remarkable substrate selectivity opens new opportunities for sustainable organic synthesis.

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