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The isobutylene carbocation (CH 3 ) 2 C=CH + was obtained in amorphous and crystalline salts with the carborane anion CHB 11 Cl 11  - . The cation was characterized by X-ray crystallography and IR spectroscopy. Its crystal structure shows a relatively uniform ionic interaction of the cation with the surrounding anions, with a slightly shortened distance between the C atom of the =CH group and the Cl atom of the anion, pointing to a higher positive charge on this group. In the amorphous phase, the asymmetric interaction of the cation with the anion increases, approaching ion pairing. This gives rise to a strong hyperconjugation between the two CH 3 groups and the 2p z orbital of the central carbon sp 2 atom (the red shift of the CH stretch is 150 cm -1 ); this effect stabilizes the cation. Over time, as the structure of the amorphous phase becomes more ordered, the hyperconjugation weakens and disappears in the crystalline phase with the disappearance of ion pairing. The carbocation stabilization in the crystalline phase is achieved due to the transfer of a portion of the charge to the neighboring anions, whereas the charge on the C=C bond becomes the strongest: the C=C stretch frequency drops to ∼160 cm -1 relative to neutral isobutylene. The collected IR spectra for the optimized cation under vacuum (in the 6-311G ++ (d, p) basis for all HF, MP2, and DFT calculations) predict that a positive charge on the C=C bond increases its stretching frequency; this computational result contradicts the experimental data, perhaps because it does not take into account the significant impact of the environment.

Unsaturated Vinyl-Type Carbocation [(CH3)2C═CH]+ in Its Carborane Salts

Unsaturated Vinyl-Type Carbocation [(CH₃)₂C═CH]⁺ in Its Carborane Salts