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Heavy metal ions represent one of the most toxic and environmentally harmful pollutants of water sources. This work reports the development of a novel chelating nitrogen-doped carboxylated porous carbon (ND-CPC) adsorbent for the effective removal of the heavy metal ions Pb(II), Hg(II), and Cr(VI) from contaminated and polluted water sources. The ND-CPC adsorbent is designed to combine four different types of nitrogen functional groups (graphitic, pyrrolic, pyridinic, and pyridine oxide) with the carboxylic acid functional groups within a high surface area of 1135 ± 20 m 2 /g of the porous carbon structure. The ND-CPC adsorbent shows exceptionally high adsorption affinity for Pb(II) with a capacity of 721 ± 14 mg/g in addition to high uptake values of 257 ± 5 and 104 ± 2 mg/g for Hg(II) and Cr(VI), respectively. The high adsorption capacity is also coupled with fast kinetics where the equilibrium time required for the 100% removal of Pb(II) from 50 ppb and 10 ppm concentrations is 30 s and 60 min, respectively. Even with the very high concentration of 700 ppm, 74% uptake of Pb(II) is achieved within 90 min. Removal efficiencies of 100% of Pb(II), 96% of Hg(II), 91% of Cu(II), 82% of Zn(II), 25% of Cd(II), and 13% of Ni(II) are achieved from a solution containing 10 ppm concentrations of these ions, thus demonstrating excellent selectivity for Pb(II), Hg(II), and Cu(II) ions. Regeneration of the ND-CPC adsorbent shows excellent desorption efficiencies of 99 and 95% for Pb(II) and Cr(VI) ions, respectively. Because of the fast adsorption kinetics, high removal capacity and excellent regeneration, stability, and reusability, the ND-CPC is proposed as a highly efficient remediation adsorbent for the solid-phase removal of Pb(II), Hg(II), and Cr(VI) from contaminated water.

Multifunctional Binding Sites on Nitrogen-Doped Carboxylated Porous Carbon for Highly Efficient Adsorption of Pb(II), Hg(II), and Cr(VI) Ions