Oxidative Dehydrogenation of Hydrazobenzenes toward Azo Compounds Catalyzed by tert-Butyl Nitrite in EtOH | Zendy

Zhiqiang Wang | Zendy; JiangXi Yu | Zendy; Shan-Qin Bai | Zendy; Bang Liu | Zendy; Chengyong Wang | Zendy; JinHeng Li | Zendy

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Oxidative Dehydrogenation of Hydrazobenzenes toward Azo Compounds Catalyzed by tert-Butyl Nitrite in EtOH

Author(s) -

Zhiqiang Wang,

JiangXi Yu,

Shan-Qin Bai,

Bang Liu,

Chengyong Wang,

JinHeng Li

Publication year - 2020

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.0c04348

Subject(s) - dehydrogenation , nitrite , oxidative phosphorylation , catalysis , chemistry , nitration , environmentally friendly , functional group , organic chemistry , photochemistry , nitrate , biochemistry , polymer , biology , ecology

We describe a tert -butyl nitrite-catalyzed oxidative dehydrogenation of hydrazobenzenes for producing azobenzenes. This method proceeds at ambient temperature and under an atmospheric environment by employing eco-friendly EtOH as the medium, representing a mild, general route to the synthesis of various symmetrical and nonsymmetrical azobenzenes in excellent yields with broad functional group tolerance.

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