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Study on the Synthesized Rosin Glyceride over LaZSM-5 Zeolite Catalyst Synthesized by the in Situ Method
Author(s) -
Xiaoxiao Wang,
Fang Guo,
Yue Yu,
Zhenmin Liu,
YingChun Wang,
Hongyan Sun,
Xianjun Liu,
Yongbing Xue,
Xianxian Wei,
Shaoqing Guo
Publication year - 2020
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.0c03427
Subject(s) - zeolite , rosin , catalysis , glyceride , yield (engineering) , in situ , lewis acids and bases , chemistry , organic chemistry , lewis acid catalysis , materials science , resin acid , composite material , fatty acid
LaZSM-5 zeolite was synthesized by the in situ method and used as catalysts to catalyze the synthesis of rosin glyceride. As a comparison, ZSM-5 was also synthesized and used as catalysts to catalyze the synthesis of rosin glyceride. The synthesized ZSM-5 and LaZSM-5 zeolite catalysts were characterized and analyzed. The experimental results showed that the in situ synthesis of LaZSM-5 made La into the skeleton of ZSM-5 zeolite and increased the amount of Lewis acid on the LaZSM-5 zeolite. Also, Lewis acid was the key to liquid-phase esterification reaction. Compared with ZSM-5 zeolite, LaZSM-5 zeolite contributed to a higher yield and better stability as a catalyst for the synthesis of rosin glycerides.

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