Numerical Investigation of the Effects of Coke on Transport Properties in an Oxidative Fuel Cell Reformer

Experimental investigations on the technical viability of solid oxide fuel cells to replace internal combustion engines in automobiles have increased in recent years. However, the performance and stability of catalysts in the presence of carbon is key for the commercial success of fuel cell reformers. In this paper, finite element method was used to study the effect of coke deposition on heat and mass transfer during the catalytic partial oxidation of ethanol in a packed bed reactor. The properties of Ni/Al 2 O 3 catalyst bed were investigated after being subjected to several hours of carbon buildup. Bed permeability, porosity, and temperature distribution were significantly affected after just 1500 s of reaction time. It was observed that void fraction and permeability became nonuniform across the bed. These two parameters decreased with axial position, and the difference became more pronounced with time. A decrease in bed porosity reduced the bed temperature due to an increase in effective thermal conductivity and ethanol conversion and hydrogen selectivity decreased as a result. Thus, it was concluded that heat transfer becomes a limiting factor in reforming reactions in the presence of carbon. Production distribution before deactivation was also studied, and it was observed that a maximum ethanol conversion of 100% was achieved at 600 °C and a C/O ratio of 1.0. Finally, results from the reactions were compared to that of a different study to validate the reaction mechanism and similar results were found in the literature.