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Photocatalytic Activity Investigation of α-Zirconium Phosphate Nanoparticles Compositing with C3N4 under Ultraviolet Light
Author(s) -
Song Qing,
Hong Chen,
Lijuan Han,
Zhongbin Ye,
Leiting Shi,
Zheng Shu,
Lei Chen,
Liang Xu,
Qiaoqiao Xu
Publication year - 2020
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.0c03040
Subject(s) - nanomaterials , materials science , zirconium phosphate , photocatalysis , compositing , photodegradation , fourier transform infrared spectroscopy , ultraviolet , chemical engineering , phosphate , nanotechnology , chemistry , optoelectronics , catalysis , computer science , organic chemistry , artificial intelligence , image (mathematics) , engineering
In order to further develop efficient ultraviolet light-driven photocatalysts for environmental application, α-zirconium phosphate (α-ZrP) and carbon nitride (C 3 N 4 ) were synthesized, respectively. Then, C 3 N 4 -ZrP compositing nanomaterials were prepared by compositing α-ZrP nanocrystals and C 3 N 4 with different mass ratios. C 3 N 4 -ZrP compositing nanomaterials were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The results illustrated that α-ZrP and C 3 N 4 were successfully composited, and the polarization of the compositing nanomaterials was reduced compared with raw materials. The photocatalytic performances of C 3 N 4 -ZrP compositing nanomaterials with different mass ratios were studied by photodegradation of RhB under ultraviolet irradiation. All of the degradation rates of the C 3 N 4 -ZrP compositing nanomaterials system were achieved more than 90% after 18 min. When the mass ratio of C 3 N 4 -ZrP compositing nanomaterials is 2:1, the degradation efficiency achieved 99.95%, which is more efficient than other tested mass ratios. The result indicated the possibility of utilizing C 3 N 4 -ZrP compositing nanomaterials for environmental pollutants degradation.

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