Effect of Addition of Polyaniline on Polyethylene Oxide and Polyvinyl Alcohol for the Fabrication of Nanorods
Author(s) -
Nabeel Z. Al-Hazeem,
Naser M. Ahmed
Publication year - 2020
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.0c02802
Subject(s) - nanorod , polyvinyl alcohol , materials science , polyaniline , nanofiber , photoluminescence , polymer , electrospinning , scanning electron microscope , chemical engineering , fabrication , polymer chemistry , nanotechnology , composite material , polymerization , optoelectronics , medicine , alternative medicine , pathology , engineering
For the first time, the fabrication of novel nanorods by the addition of polyaniline (PANI) to polyethylene oxide (PEO) and polyvinyl alcohol (PVA) polymers through electrospinning method is investigated. Field emission scanning electron microscopy observations reveal the formation of nanofibers and nanorods having diameters in the range of 26.87-139.90 nm and 64.11-122.40 nm, respectively, and lengths in the range of 542.10 nm to 1.32 μm. Photoluminescence (PL) analysis shows the presence of peaks which are characteristic of isotactic polymers (363-412, 529-691 nm), 412-529 nm for PVA/PEO and 363-691 nm for PVA/PEO/PANI. PL spectra also show peak bonding at a wavelength of 552 nm. Manufacture of nanorods by electrospinning method gives better options for controlling the diameter and length of nanorods.
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