What Is the Main Feature Distinguishing the Through-Space Interactions in Cyclophanes from Their Aliphatic Analogues? | Zendy

Irena Majerz | Zendy; T. Dziembowska | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

What Is the Main Feature Distinguishing the Through-Space Interactions in Cyclophanes from Their Aliphatic Analogues?

Author(s) -

Irena Majerz,

T. Dziembowska

Publication year - 2020

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.0c02671

Subject(s) - cyclophane , chemistry , intramolecular force , steric effects , ring (chemistry) , benzene , benzene derivatives , computational chemistry , stereochemistry , crystallography , crystal structure , organic chemistry , chemical synthesis , biochemistry , in vitro

Classical cyclophanes with two benzene rings have been compared with cyclophanes with one benzene ring replaced with an aliphatic part and aliphatic compounds, which are cyclophane analogues. Analysis of geometry, atomic charges, and aromatic and steric energy and investigation of intramolecular noncovalent interactions and charge mobility show that there is no special feature that distinguishes the classical cyclophanes from aliphatic analogues, so the definition of cyclophanes can be extended to other compounds.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research