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Developing an effective method for monitoring fluoride ion in biological samples is meaningful because fluoride ion plays a vital role in biological processes. In this contribution, a simple water-soluble ESIPT fluorescent probe 2-((4-(( tert -butyldiphenylsilyl)oxy)-1,3-dioxoisoindolin-2-yl)methyl)-1-ethylpyridin-1-ium iodide ( SPI ) was constructed for monitoring fluoride ion. The probe SPI containing pyridinium salt group exhibited preeminent water solubility. The probe SPI introducing a trimethyldiphenylsilyl ether recognition group displayed excellent selectivity for fluoride ion over other biologically relevant species. Additionally, the probe SPI exhibited a fast response for a fluoride ion, suggesting that it could provide real-time fluoride ion detection. Importantly, the probe could detect fluoride ion with a linear range of 0-70.0 × 10 -6 M and a low detection limit of 1.16 × 10 -6 M. Furthermore, probe SPI could detect fluoride ion with a large Stokes shift (98 nm), which was attributed to ESIPT fluorescence sensing process. At last, probe SPI was successfully employed to monitor fluoride ion in living cells.

A Simple Water-Soluble ESIPT Fluorescent Probe for Fluoride Ion with Large Stokes Shift in Living Cells