Synthesis, Morphology, and Luminescence Properties of Poly(urethane-acrylate) Nanowires Bonding with the Eu(III) Complex | Zendy

Lijun Gao | Zendy; Liuyang Li | Zendy; Yunqiu Li | Zendy; Min Li | Zendy; Cong Li | Zendy; Jing Cui | Zendy; Haoran Yang | Zendy; Liming Zhou | Zendy; Shaoming Fang | Zendy

Open Access

Synthesis, Morphology, and Luminescence Properties of Poly(urethane-acrylate) Nanowires Bonding with the Eu(III) Complex

Author(s) -

Lijun Gao,

Liuyang Li,

Yunqiu Li,

Min Li,

Cong Li,

Jing Cui,

Haoran Yang,

Liming Zhou,

Shaoming Fang

Publication year - 2020

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.0c01896

Subject(s) - nanowire , luminescence , materials science , copolymer , europium , acrylate , anodizing , polymerization , chemical engineering , photoluminescence , nanotechnology , polymer , polymer chemistry , composite material , aluminium , optoelectronics , engineering

Photoluminescent poly(urethane-acrylate) (PUA) nanowires are designed and synthesized through copolymerization of a presynthesized-europium (Eu) complex with active vinyl groups and a vinyl functionalized PUA macromonomer matrix, initiated by azobisisobutyronitrile. This procedure provides a method to prepare PUA-Eu nanowires through in situ polymerization. Based on this, a series of PUA-Eu nanowires with diameters of 80-300 nm are successfully obtained in templates of anodized aluminum oxide by in situ polymerization. The obtained PUA-Eu nanowires display different morphologies such as sharp, round, and flat head by controlling the casting conditions. Furthermore, the PUA-Eu nanowires exhibit unique luminescence properties provided through Eu(III) elements, and the luminescence intensity significantly enhances with the increase in Eu complex concentration. PUA-Eu nanowires have longer fluorescence lifetimes than that of Eu complexes and PUA-Eu plates.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research