A New Experimental Approach to Evaluate Coal Particles Floatability: Bubble–Particle Attachment and Detachment Kinetics
Author(s) -
Lijuan Sun,
Yaowen Xing,
Haichang Yang,
Yijun Cao,
Xiahui Gui
Publication year - 2020
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.0c01630
Subject(s) - bubble , kinetics , particle (ecology) , chemistry , reaction rate constant , froth flotation , contact angle , materials science , mechanics , composite material , geology , physics , oceanography , organic chemistry , quantum mechanics
Coal floatability evaluation is of vital importance in the prediction of flotation results and the design of a flotation flowsheet. In this work, a new experimental approach based on bubble-particle attachment kinetics (BPAK) and bubble-particle detachment kinetics (BPDK) were proposed to evaluate the floatability of coal particles. During attachment and detachment processes, a variation of coating angles θ( t ) for different density coal particles were measured and fitted to a first-order model. Modified attachment rate constant k a * and modified detachment rate constant k d * were used as yardsticks of floatability. For comparison, flotation kinetics, induction time, and contact angle measurements were also conducted. A consistent sequence of floatability was obtained as: -1.4 > 1.4-1.6 > +1.6 g/cm 3 . The modified flotation rate constant k * obtained in flotation kinetics was used as a yardstick to assess the accuracy of floatability evaluation methods. By individually fitting k * to parameters obtained in other tests, a simple and close linear relationship between k * and modified attachment rate constant k a * was established, rather than 1/ k d * in BPDK tests, induction time t ind , or (1 - cosα) in contact angle measurements. Consequently, k a * is thought to be a better criterion as k * could be quantitatively predicted by BPAK tests. Throughout this work, BPAK is an effective method to evaluate coal floatability.
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