Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes | Zendy

Christina Erken | Zendy; Carsten Hindemith | Zendy; Thomas Weyhermüller | Zendy; Markus Hölscher | Zendy; Christophe Werlé | Zendy; Walter Leitner | Zendy

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Hydroamination of Aromatic Alkynes to Imines Catalyzed by Pd(II)–Anthraphos Complexes

Author(s) -

Christina Erken,

Carsten Hindemith,

Thomas Weyhermüller,

Markus Hölscher,

Christophe Werlé,

Walter Leitner

Publication year - 2020

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.0c00562

Subject(s) - hydroamination , catalysis , cationic polymerization , chemistry , intermolecular force , organic chemistry , combinatorial chemistry , alkyne , medicinal chemistry , molecule

Herein, we report the synthesis, characterization, and catalytic performance of cationic Pd(II)-Anthraphos complexes in the intermolecular hydroamination of aromatic alkynes with aromatic amines. The reaction proceeds with 0.18 mol % of catalyst loading, at 90 °C for 4 h under neat conditions. Good to excellent yields could be obtained for a broad range of amines and alkynes.

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