Regulated Dynamics with Two Monolayer Steps in Vapor–Solid–Solid Growth of Nanowires
Author(s) -
E. BelletAmalric,
Federico Panciera,
G. Patriarche,
Laurent Travers,
M. den Hertog,
JeanChristophe Harmand,
Frank Glas,
J. Cibért
Publication year - 2022
Publication title -
acs nano
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.554
H-Index - 382
eISSN - 1936-086X
pISSN - 1936-0851
DOI - 10.1021/acsnano.1c10666
Subject(s) - monolayer , nanowire , materials science , solid solution , heterojunction , transmission electron microscopy , nanotechnology , cadmium telluride photovoltaics , chemical physics , optoelectronics , chemistry , metallurgy
The growth of ZnTe nanowires and ZnTe-CdTe nanowire heterostructures is studied by in situ transmission electron microscopy. We describe the shape and the change of shape of the solid gold nanoparticle during vapor-solid-solid growth. We show the balance between one monolayer and two monolayer steps, which characterizes the vapor-liquid-solid and vapor-solid-solid growth modes of ZnTe. We discuss the likely role of the mismatch strain and lattice coincidence between gold and ZnTe on the predominance of two monolayer steps during vapor-solid-solid growth and on the subsequent self-regulation of the step dynamics. Finally, the formation of an interface between CdTe and ZnTe is described.
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